{"created":"2023-06-20T15:28:41.665080+00:00","id":8177,"links":{},"metadata":{"_buckets":{"deposit":"bbcaeb43-df0f-4bbb-b128-0af80485c163"},"_deposit":{"created_by":12,"id":"8177","owners":[12],"pid":{"revision_id":0,"type":"depid","value":"8177"},"status":"published"},"_oai":{"id":"oai:ouj.repo.nii.ac.jp:00008177","sets":["389:522"]},"author_link":["10180","10178","10179","10181"],"item_10001_biblio_info_7":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2004-01-01","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"19","bibliographicPageEnd":"2147","bibliographicPageStart":"2146","bibliographic_titles":[{},{"bibliographic_title":"Chemical communications (Cambridge, England)","bibliographic_titleLang":"en"}]}]},"item_10001_description_5":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"When recrystallizations were performed using a mixture of 12 D,L-amino acids (alanine, aspartic acid, arginine, glutamic acid, glutamine, histidine, leucine, methionine, serine, valine, phenylalanine, and tyrosine) with excess D,L-asparagine, all amino acids with the same configuration as asparagine were preferentially co-crystallized, indicating that it is the nature of a mixture of racemic amino acids to produce a spontaneous high enantiomeric excess.","subitem_description_type":"Abstract"}]},"item_10001_description_6":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"When recrystallizations were performed using a mixture of 12 D,L-amino acids (alanine, aspartic acid, arginine, glutamic acid, glutamine, histidine, leucine, methionine, serine, valine, phenylalanine, and tyrosine) with excess D,L-asparagine, all amino acids with the same configuration as asparagine were preferentially co-crystallized, indicating that it is the nature of a mixture of racemic amino acids to produce a spontaneous high enantiomeric excess.","subitem_description_type":"Other"}]},"item_10001_relation_13":{"attribute_name":"PubMed番号","attribute_value_mlt":[{"subitem_relation_type":"isIdenticalTo","subitem_relation_type_id":{"subitem_relation_type_id_text":"15467844","subitem_relation_type_select":"PMID"}}]},"item_10001_relation_14":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isIdenticalTo","subitem_relation_type_id":{"subitem_relation_type_id_text":"10.1039/b409941a","subitem_relation_type_select":"DOI"}}]},"item_10001_source_id_9":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"1359-7345","subitem_source_identifier_type":"ISSN"}]},"item_10001_version_type_20":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Kojo, 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enantiomeric...","url":"https://ouj.repo.nii.ac.jp/record/8177/files/EarthModel.pdf"},"version_id":"420f6a41-84c6-41fe-a721-662d1a489f76"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"Amino Acids","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"Asparagine","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"Chromatography, High Pressure Liquid","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"Crystallization","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"Stereoisomerism","subitem_subject_language":"en","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal 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biosphere.","subitem_title_language":"en"}]},"item_type_id":"10001","owner":"12","path":["522"],"pubdate":{"attribute_name":"公開日","attribute_value":"2014-07-22"},"publish_date":"2014-07-22","publish_status":"0","recid":"8177","relation_version_is_last":true,"title":["Racemic D,L-asparagine causes enantiomeric excess of other coexisting racemic D,L-amino acids during recrystallization: a hypothesis accounting for the origin of L-amino acids in the biosphere."],"weko_creator_id":"12","weko_shared_id":-1},"updated":"2023-06-20T16:12:57.772287+00:00"}